Crystal Chemistry Creations!
Materials You'll Need:
- Borax powder (sodium tetraborate - found in laundry aisle)
- Wide-mouth glass jar or heat-resistant beaker (approx. 500 mL)
- Boiling water
- Measuring cup and measuring spoons (tablespoon)
- Pipe cleaner
- String or fishing line
- Popsicle stick or pencil
- Optional: Food coloring
- Optional: Magnifying glass
- Safety goggles
- Pot holder or oven mitt
Introduction: The Magic of Crystals
Have you ever wondered how glittering gemstones form, or how snowflakes get their intricate shapes? It's all about chemistry! Crystals are solid materials where the atoms, molecules, or ions are arranged in a highly ordered, repeating pattern, forming a crystal lattice. Today, we're going to become crystal chemists and grow our own beautiful crystals using a common household item.
Background Chemistry: Solution Secrets
To grow crystals, we need to understand solutions. A solution is a mixture where one substance (the solute) dissolves evenly into another (the solvent). Think salt (solute) dissolving in water (solvent).
Solubility is how much solute can dissolve in a solvent at a certain temperature. Usually, more solid solute can dissolve in a hotter solvent.
When you dissolve the maximum amount of solute possible at a given temperature, the solution is saturated. If you try to add more solute, it won't dissolve.
Now for the cool part: supersaturation! If you create a saturated solution at a high temperature and then let it cool slowly without disturbing it, you can actually keep more solute dissolved than would normally be possible at the lower temperature. This unstable state is called supersaturation. It's the key to growing crystals!
As the supersaturated solution cools, the solvent can't hold onto all the excess solute. The solute molecules start looking for places to settle down and arrange themselves into that ordered crystal structure. This process often starts around tiny imperfections or a 'seed' – a process called nucleation – and then the crystal grows layer by layer.
Activity: Let's Grow Borax Crystals!
Safety First! Wear safety goggles. Boiling water is very hot – ask for help if needed and use pot holders. Borax is for crafting, not eating – keep it away from mouth and wash hands after handling.
- Prepare your Shape: Cut a pipe cleaner into a desired shape (a star, spiral, initial – keep it small enough to fit inside the jar without touching the sides or bottom).
- Attach the String: Tie one end of the string firmly to your pipe cleaner shape. Tie the other end to the middle of the popsicle stick or pencil. Adjust the string length so that when the pencil rests across the mouth of the jar, the pipe cleaner hangs inside without touching the bottom or sides. Set this aside for now.
- Make the Supersaturated Solution: Measure about 3 tablespoons of Borax powder for every 1 cup of boiling water. You'll need enough solution to fully submerge your pipe cleaner shape in the jar. It's better to make slightly more than you think you need.
- Dissolve the Borax: Carefully pour the boiling water into your glass jar (use a pot holder!). Add the Borax powder, one tablespoon at a time, stirring well after each addition until it dissolves. Keep adding Borax and stirring until no more will dissolve and you see a little bit settling at the bottom. This ensures the solution is saturated at the high temperature.
- Optional - Add Color: If you want colored crystals, add a few drops of food coloring to the solution now and stir.
- Set Up Your Crystal Farm: Carefully lower the pipe cleaner shape into the hot Borax solution in the jar, resting the pencil across the jar's mouth. Make sure the pipe cleaner is fully submerged and not touching the jar.
- Patience is Key: Place the jar in a location where it won't be disturbed. Let it sit undisturbed overnight (or for at least 6-8 hours). Resist the urge to move it! Slow cooling allows for larger, more well-defined crystals.
- Observe and Harvest: The next day, carefully lift the pencil and your beautiful, crystal-covered shape out of the solution. Let it dry on a paper towel. Observe the crystals closely. Use a magnifying glass if you have one! Notice their shape and how they've grown on the pipe cleaner.
Why Did That Happen? The Science Explained
We created a supersaturated solution of Borax in hot water. As the water cooled slowly, its ability to hold the dissolved Borax decreased. The 'extra' Borax molecules needed somewhere to go! They began to deposit onto the surface of the pipe cleaner (which acted as a nucleation site), arranging themselves into their specific crystalline structure. The longer and more slowly it cooled, the more Borax came out of solution and added to the growing crystals.
Discussion & Exploration
- What shape are your crystals? (Borax crystals tend to be somewhat blocky or monoclinic).
- Did crystals form anywhere else, like the sides or bottom of the jar? Why?
- How might changing the cooling rate (e.g., putting it in the fridge vs. leaving it at room temperature) affect crystal size? (Faster cooling usually means smaller crystals).
- What other substances could you try crystallizing? (Sugar for rock candy, Epsom salt, Alum).
Wrap-up & Assessment
Explain in your own words what supersaturation is and why it's important for growing crystals. Describe the steps you took and what you observed. You could even draw a picture of your crystal creation and label the key parts of the process!